<style type="text/css"> 
div
{
width:100px;
height:100px;
background:red;
transition:width 2s;
-moz-transition:width 2s; /* Firefox 4 */
-webkit-transition:width 2s; /* Safari and Chrome */
-o-transition:width 2s; /* Opera */
}
 
div:hover
{
width:300px;
}
</style>
<div></div>

<style type="text/css"> 
div
{
width:100px;
height:100px;
background:red;
position:relative;
animation:mymove 5s infinite;
-moz-animation:mymove 5s infinite; /*Firefox*/
-webkit-animation:mymove 5s infinite; /*Safari and Chrome*/
}
@keyframes mymove
{
from {left:0px;}
to {left:200px;}
}
@-moz-keyframes mymove /*Firefox*/
{
from {left:0px;}
to {left:200px;}
}
@-webkit-keyframes mymove /*Safari and Chrome*/
{
from {left:0px;}
to {left:200px;}
}
</style>
<div></div>